Dichloridotriphenylantimony(V)–bis(pyrrolidin-1-ylthiocarbonyl) disulfide (1/1)
نویسندگان
چکیده
The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis-(pyrrolidinylthio-carbamo-yl) mol-ecule and a dichloro-triphenyl-anti-mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio-carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol-ecules are connected by weak C-H⋯S and C-H⋯Cl hydrogen-bonding inter-actions into two one-dimensional supra-molecular chains.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007